Pdf the use of carbon nanotubes with and without nitrogen. Effects of nitrogen doping on the structure of carbon. Nitrogen doping mechanism in small diameter singlewalled carbon nanotubes. Carbon nanotubes cnts and nitrogendoped carbon nanotubes cnx were synthesized by the floating catalyst chemical vapor deposition fccvd method. It is caused by that lengths of bonds nc and cc differ a little 1. Jan 15, 2020 among the various potential dopants, nitrogen is presently considered as an excellent doping component for carbon based materials. Effect of sulfur on enhancing nitrogendoping and magnetic properties of carbon nanotubes tongxiang cui1, ruitao lv1, zhenghong huang1, feiyu kang1, kunlin wang2, dehai wu2 abstract sulfur s is introduced as an additive in the growth atmosphere of carbon nanotubes cnts in. The two types of mwnts were found to possess similar strengths but different load. Carbon nanotubes thermal and chemical durability nitrogen doping introduction nitrogen doped carbon nanotubes cn x tubes have attracted particular research interest because of their applications in producing different types of nanodevices with tuning properties such as nanoscale electronics huang et al. We first provide an introduction to the field of nitrogen doped carbon nanotubes ncnts and. Nitrogen doping effects on carbon nanotubes and the origin of. In this case, dopingrefers tothe substitution of a carbon atom with oth er elements such as boron or nitrogen, andis expectedto have significant impact on th e charge transport properties of the nanotubes.
Nitrogendoped carbon nanotubes synthesised by pyrolysis of. The use of carbon nanotubes with and without nitrogen doping as support for ruthenium catalysts in the ammonia decomposition reaction. There is a huge interest in the use of carbon nanotubes in biology, and substitutional doped tubes may prove to be the material of choice for these applications. The book presents examples of specific calculations for doping of carbon nanotubes with oxygen, hydrogen, nitrogen and boron, together with numerous experimental results and a comparison with the authors thermodynamic calculations. Promotion effects of nitrogen doping into carbon nanotubes. Femn nanoparticles encapsulated in nitrogendoped carbon nanotubes as a peroxymonosulfate activator for acetamiprid degradation pijun duan, a tengfei ma, a yue yue, b yanwei li, b xue zhang, a yanan shang, a baoyu gao, a qingzhu zhang, b qinyan yue a and xing xu a. Isolated single wall carbon nanotubes swnts were prepared on bare quartz and sio2si substrates using a chemical vapor deposition process in which xylene was used as the carbon source.
In the xray photoelectron spectroscopy observations. Proposed growth models for ncnt synthesis are also reported. Three different catalysts co, fe, and ni were used to synthesize nitrogendoped cnts ncnts by chemical vapor deposition technique. We demonstrate that nitrogen doping occurs as single atoms in different bonding. Therefore,itshouldbepossibletoavoidthose detrimental functionalization processes using strong acid and to attach pt nanoparticles onto the surface of cnx e. This dissertation discusses the influence of nitrogen doping ndoping on the electronic and catalytic properties of carbon nanotubes cnts. The electrochemical nitrogen reduction reaction nrr as an energyefficient approach for ammonia synthesis is hampered by the low ammonia yield and ambiguous reaction mechanism. The doping of carbon nanotubes with nitrogen and their potential applications p. The soconstructed fencnts catalyst presents superb catalytic performance in fts with high selectivity for lower olefins of up to 46. Nitrogendoped carbon nanotubepolymer nanocomposites towards. The inner diameter and wall thickness of the pncnts are about 55 nm and 22 nm, respectively. Pdf nitrogendoped carbon materials, including nitrogendoped carbon nanotubes ncnts and nitrogendoped graphene ng, have attracted increasing. Herein, phosphorusdoped carbon nanotube pcnts is developed as an efficient metalfree electrocatalyst for nrr with a remarkable nh3 yield of 24. Concentration profiles derived from electron energyloss line spectra show that boron and nitrogen are correlated in a onetoone ratio.
Carbon nanotubes, cvd synthesis, nitrogen doping, acetonitrile, fecocaco 3 catalyst. Nitrogendoped carbon nanotube and graphene materials. Nitrogendoped carbon nanotube and graphene materials for. Carbon c nanotubes nt nowadays represent one of the most active research fields. Pdf growth, nitrogen doping and characterization of.
Jan 12, 2011 the effective doping of nitrogen into cnts is mainly achieved in situ during cnt growth 1216, 19, and ndoping content is usually controlled by adjusting the ratio of carbon source to nitrogen source 16, 19, which is disadvantageous for increasing the doping content of cnts produced with liquid carbon source. Jan 14, 2016 although nitrogen doped carbon nanotubes are a very poor hydrogen oxidation catalyst, as a support, it increases the catalytic performance of nickel nanoparticles by a factor of 33 mass activity. Nitrogen is one of promising dopants for carbonbased materials since it is a neighbouring element to carbon in periodic table. Nitrogendoped carbon materials, including nitrogendoped carbon nanotubes.
Pichler a a faculty of physics, university of vienna, strudlhofgasse 4, a1090 vienna, austria. Nitrogen doping of single and multiwalled carbon nanotubes is of great interest both fundamentally, to explore the effect of dopants on quasi1d electrical conductors, and for applications such. Nitrogen doping effects on carbon nanotubes and the origin. The synthesis of nitrogendoped multiwalled carbon nanotubes. These properties have been studied using a variety of techniques, in order to both qualitatively and quantitatively analyze the relationship between the nitrogen concentration and observed properties. Electronic properties of nitrogendoped carbon nanotubes with. Effect of nitrogen doping on raman spectra of multi. Bulk nitrogen doping can efficiently improve the catalytic performance of carbon nanotubes cnt in oxidative dehydrogenation of propane odh. Effects of nitrogendoped multiwall carbon nanotubes on murine. The two types of mwnts were found to possess similar strengths but different. Synthesis of nitrogen doped carbon nitrogen n is a neighboring element of carbon in the periodic table, and its electronegativity 3. However, although this is true in the case of boron doping, the ionization potential was not a correct indicator. Nitrogendoped carbon nanotubes ncnts were synthesized by pyrolysis of 4pyridine4ylmethylideneaminophenylferrocene in a solution of either acetonitrile or toluene as carbon source.
Effect of sulfur on enhancing nitrogendoping and magnetic. Nitrogen doped carbon nanotubes ncnts were synthesized by pyrolysis of 4pyridine4ylmethylideneaminophenylferrocene in a solution of either acetonitrile or toluene as carbon source. Nickel supported on nitrogendoped carbon nanotubes as. The doping of carbon nanotubes with nitrogen and their potential applications, carbon, 482010 575586. Femn nanoparticles encapsulated in nitrogendoped carbon. Nitrogendoped carbon nanotubes cnx contain nitrogenated sites that are chemicallyactive. Unusually high dispersion of nitrogen doped carbon nanotubes in dna solution. Nitrogendoped carbon materials, including nitrogendoped carbon nanotubes ncnts and nitrogendoped graphene ng, have attracted increasing attention for oxygen reduction reaction orr in metalair batteries and fuel cell applications, due to their optimal properties including excellent electronic conductivity, 4e. This is mainly inspired in the possible applications such structures can have. Substitutional doping with heteroatoms is known to be an effective way to tune the electronic properties of the cnts. One way for achieving thiscontrol is by carrying out doping. Phosphorusdoping activates carbon nanotubes for efficient.
Among the various potential dopants, nitrogen is presently considered as an excellent doping component for carbonbased materials. The literature regarding the study of properties and applications of pristine cnt has progressed enormously in the recent years and a great interest has been lately observed towards improving and controlling their properties through different functionalization methods. This study investigates the impact of nitrogen doping on the performance of carbon nanotube cntpolymer nanocomposites for thermoelectric applications. Impact on electronic properties and growth selectivity hamid reza barzegar, eduardo graciaespino, tiva sharifi, florian nitze, and thomas wagberg. The incorporation of n atom into a graphene lattice plane could modulate the local electronic properties, as it could form strong bonds with carbon atoms because of its. The effective doping of nitrogen into cnts is mainly achieved in situ during cnt growth 1216, 19, and ndoping content is usually controlled by adjusting the ratio of carbon source to nitrogen source 16, 19, which is disadvantageous for increasing. Effect of nitrogen doping on the electronic and catalytic. Preparation and photocatalytic properties of sno2 coated on. Yale university researchers have developed a simple method for controlling the doping of carbon nanotubes cnts, a chemical process that. Composite sheets and nanotubes of different morphologies containing carbon, boron, and nitrogen were grown in the electric arc discharge between graphite cathodes and amorphous boronfilled graphite anodes in a nitrogen atmosphere.
Thermal and chemical durability of nitrogendoped carbon. Nano express open access effect of sulfur on enhancing. Pyridinetype in which each n atom is bonded to two carbon atoms. Nitrogen doping mechanism in small diameter singlewalled. Carbon nanotubes thermal and chemical durability nitrogen doping introduction nitrogendoped carbon nanotubes cn x tubes have attracted particular research interest because of their applications in producing different types of nanodevices with tuning properties such as nanoscale electronics huang et al. The doping of carbon nanotubes with nitrogen and their. Dec 08, 2017 in this video, i have discussed about doping of cnt by n, structural change and its application. Pt nanoparticles were deposited onto the two catalyst supports with the ethylene glycol reduction method. Doping graphitic and carbon nanotube structures with boron. As such, doping carbon nanotubes with nitrogen heteroatoms as in the ncnt electrodes can efficiently create the metalfree active sites for electrochemical reduction of o 2. Nitrogen and boron doping in carbon nanotubes chris ewels. We report on the usage of a simple microfabricated device that works in conjunction with a quantitative nanoindenter within a scanning electron microscope sem chamber, for the in situ quantitative tensile testing of individual catalytically grown pristine and nitrogendoped multiwall carbon nanotubes mwnts.
First principles calculation of field emission from carbon. Pdf nitrogen doping of single and multiwalled carbon nanotubes is of great interest both fundamentally, to explore the effect of dopants on. Pdf nitrogendoped carbon nanotube and graphene materials. Photoassisted electronic transport in impuritydoped carbon. Nitrogen doped carbon nanotubes from organometallic.
Nitrogendoped carbon nanotubes ncnts can be produced through five main methods. N 2 physisorption, xps, xrd, tem, and co chemisorption were employed to investigate the effects of nitrogen doping on the structure of cnts and the state of ru particles supported on cnts. Owens, based on theoretical computations, expected that both boron and nitrogen doping will not enhance eld emission based on the fact that they increase the ionization energy of carbon nanotubes. The effective doping of nitrogen into cnts is mainly achieved in situ during cnt growth 1216,19, and ndoping content is usually controlled by adjusting the ratio of carbon source to nitrogen source 16,19, which is disadvantageous for increasing the doping content of.
Jan 15, 2020 the electrochemical nitrogen reduction reaction nrr as an energyefficient approach for ammonia synthesis is hampered by the low ammonia yield and ambiguous reaction mechanism. The bulk structure and the surface texture of cnts remain unchanged by such nitrogen doping. Jan 12, 2011 the effective doping of nitrogen into cnts is mainly achieved in situ during cnt growth 1216,19, and n doping content is usually controlled by adjusting the ratio of carbon source to nitrogen source 16,19, which is disadvantageous for increasing the doping content of cnts produced with liquid carbon source. The asobtained sno 2 cnx composites were characterized using xray powder diffraction, scanning electron microscopy, and transmission electron microscopy. This dissertation discusses the influence of nitrogen doping n doping on the electronic and catalytic properties of carbon nanotubes cnts. Theoretical investigation on singlewall carbon nanotubes. Nitrogen doping of single and multiwalled carbon nanotubes is of great interest both fundamentally, to explore the effect of dopants on quasi1d electrical conductors, and for applications such as field emission tips, lithium storage, composites and nanoelectronic devices. The various issues related to the synthesis of nitrogen and boron. Nitrogendoped carbon nanotubepolymer nanocomposites. Various applications of carbon nanotubes require their chemical modification inorder to tunecontrol their physicochemical properties.
By means of the anchoring effect and the intrinsic basicity of nitrogendoped carbon nanotubes ncnts, iron nanoparticles were conveniently immobilized on ncnts without surface premodification. Carbon nanotubes electrontransfer nitrogen doping vertically aligned carbon nanotubes produced with in situ doping of nitrogen cn x nts during chemical vapor deposition exhibit unique structural and electrochemical properties, which are strongly correlated with their nitrogen n doping level. Oxygen and nitrogen doping in single wall carbon nanotubes. The effect of nitrogendoped multiwall carbon nanotubes cn x on the proliferation of nih3t3 murine fibroblasts is presented.
The graphitic nitrogen plays a determining role in enhancing their activity by speeding up the activation of oxygen and. Nitrogen doping on carbon nanotubes cnts was carried out using n 2 microwave plasma at the powers of 200 and 400 w. Doping of a carbon 10,0 nanotube by atom of nitrogen the atom of nitrogen also is well inscribed in geometry of a nanotube, not calling essential strain of its nanostructure figure 8. The graphitic nitrogen plays a determining role in enhancing their activity by speeding up the activation of oxygen and decreasing the overall activation energy of t. Structural study of nitrogendoping effects in bambooshaped multiwall carbon nanotubes article pdf available in applied physics letters 8415.
The nitrogen species would serve as doping heteroatoms in the formation of carbon materials, which would help to improve the conductivity and energy. Introduction since the discovery of polyhedral carbon clusters fullerenes in 1985,1 new graphitelike nanostructures such as carbon nanotubes cnts2 and related nanostructures spheres,3 onions,4 fibres,5 horns6, etc. Electronic properties of nitrogen doped carbon nanotubes with. We first provide an introduction to the field of nitrogen doped carbon nanotubes ncnts and a brief overview of their properties. Effects of nitrogendoping on the microstructure, bonding and. Researchers from the university of calgary in canada and washington state university tricities in the us manipulated the structure of cnts by introducing nitrogen between carbon atoms in cnts, and succeeded in improving the charge storage capacity of cntpolymer nanocomposites. Controlled doping of isolated swnts with nitrogen was achieved.
Although nitrogendoped carbon nanotubes are a very poor hydrogen oxidation catalyst, as a support, it increases the catalytic performance of nickel nanoparticles by a factor of 33 mass activity. Walled carbon nanotubes doped with nitrogen and boron. Atomic configuration of nitrogendoped singlewalled carbon. Mananghaya, carbon nanotubes doped with nitrogen, pyridinelike nitrogen defects and transition metal atoms, journal of korean chemical society, vol. Carbon nanotubes electrontransfer nitrogendoping vertically aligned carbon nanotubes produced with insitu doping of nitrogen cn x nts during chemical vapor deposition exhibit unique structural and electrochemical properties, which are strongly correlated with their nitrogen n doping level. Revealing the enhanced catalytic activity of nitrogendoped. Doping 10, 0semiconductor nanotubes with nitrogen and. New doping method improves properties of carbon nanotubes. Three different catalysts co, fe, and ni were used to synthesize nitrogen doped cnts ncnts by chemical vapor deposition technique. The practical background lies in the fact that defined n. In addition, nitrogendoped carbon itself has a certain activity.
Doping of carbon nanotubes sergey bulyarskiy springer. Nitrogen doped carbon nanotubes ncnts can be produced through five main methods. Pdf nitrogen doping in carbon nanotubes researchgate. Nitrogen doping effects on microstructure of multiwalled. Nov 11, 2010 we report on the usage of a simple microfabricated device that works in conjunction with a quantitative nanoindenter within a scanning electron microscope sem chamber, for the in situ quantitative tensile testing of individual catalytically grown pristine and nitrogen doped multiwall carbon nanotubes mwnts. The presence of nitrogen atoms in the graphitic sheets was assumed to have led to the formation of kinks whose motion induced by straining could have resulted in the plastic deformation of the carbon nanotubes. Figure 2 from nitrogendoped carbon nanotube and graphene. Nitrogen doping of metallic singlewalled carbon nanotubes. C was found to be the most favourable condition for ncnt growth. Effect of nitrogen doping on the mechanical properties of. The photocatalytic activity of asprepared sno 2 cnx for degradation rhodamine b under. Synthesis of nitrogendoped carbon nitrogen n is a neighboring element of carbon in the periodic table, and its electronegativity 3. The samples were prepared from toluene and acetonitrile taken in different proportion.
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